DENIM WASHING PROCESS
ABSTRACT
As
denim is one of the tradition item and the denim washing have very stable
performance. However, there are some of the comments that when the fabric has
longer washing time, use of the chemical on the washing procedure will affect
the physical performance such as the tensile strength will decrease. In order
to achieve an optimum the effect of washing process on the denim woven fabric
in different washing time, Enzyme Wash, Enzyme wash with bleach, Enzyme wash
with stone and Enzyme wash with stone and bleach were carried out for cotton
and cotton - spandex denim fabric. The effect of the washing parameters, such
as the temperature, time and pH on the result of the cotton and cotton spandex
denim after treatment were studied by assessment of the tensile physical
properties and elongation to break
KEYWORDS: Enzyme, stone, pH, elongation to
break
Origin
The word 'denim' comes
from the name of a sturdy fabric called serge, originally made in Nimes, France, by the André
family. Originally called Serge de Nimes, the name was soon shortened to denim. Denim has been used in
America since the late 18th century. Denim was traditionally colored blue with indigo dye to make blue "jeans", though
"jean" then denoted a different, lighter cotton textile; the
contemporary use of jean comes from the French word for Genoa, Italy , where the first denim
trousers were made
The
history of denim
A popular conception of
the entomology of the denim is that it is a contraction or derivative of the
french term SERGE DE NIMES. Denim was traditionally colored blue with indigo
dye to make blue “Jeans“Though “Jean“ then denoted a different , lighter cotton
textile ; the contemporary use of jean comes from the French word for Genoa
,Italy,(Genes ) , from which the first denim trousers were made .Similarly
woven traditional American cotton textile is the diagonal warp-striped hickory
cloth that was once associated with railroad men’s overalls, in which blue or
black contrasting with undyed white threads from the woven pattern . Records of
a group of New Yorkers headed for the California gold fields in 1849 show that
they took along four “hickory shirts “ apiece. Hickory cloth would later
furnish the material for some “fatigue” pantaloons and shirts in the American
civil war.
Objects
of garments washing:
1.
To develop softness in garments: Size
materials applied during manufacturing present in the fabric are removed which
enhances soft hand feel . Additional softness may be attained by using softener.
2.
To introduce fading effect: Dyes or
pigments are present in the fabric , used during coloration, are washed out
locally or partially which result fading or worn out effects in the garments.
3.
To create new fashion: Washing
Process of garments bring different outlook ( faded, color tinted etc ) thus
creating new fashion for the new generation especially for teenagers.
4.
To satisfy
the consumer: As the contraction or extraction (shrinkage ) occur due to
washing , the wearer can use the garments after purchase satisfactory
Advantages
of garments washing:
The following advantages are obtained
could be gained from the garments washing—
- Removal
of starch or size materials makes the fabric soft hand feels.
- Softness
could be increased by the addition of softener just at the last stage of
washing.
- Dirt,
spots, impurities, gum etc, if accumulated in the garments during
manufacturing could be removed.
- During
washing shrinkage may takes place, therefore after washing there is no
possibility to create such problem.
- Washed
garments could be worn directly after purchase.
- Faded
or worn out effect could introduced to the garments which creates new
fashion
- Similar
outlook can be obtained by different washing techniques.
- Comparatively
lower capital is required to set up a washing plant.
- Lower
land space and least manpower cost are required to run a washing plant.
Unavoidable changes /
limitations of garments washing
Like
other processes the garments washing is also not without some limitations. They
included as below-
- Garments
size change: Size
change takes place due to shrinkage properties of fabric. The amount of
shrinkage properties of fabric determines the size change of the garments.
- Size
material is partly removed: Unfixed dyes may remain on the
surface of the garments and it is necessary to remove completely after
washing.
TYPES OF DENIM WASH:
- Denim
washes are of following two type :–
1.
Chemical washes
- Denim
bleaching
- Enzyme
wash
- Acid
wash
2.
Mechanical washes
- Stone
wash
- Microsanding
v Chemical washes
1.
DENIM BLEACHING:
In the process a strong
oxidative bleaching agent like sodium hypochlorite or KMnO4 is added
during the washing with or without stone addition. Discoloration produced is
usually more apparent depending on strength on the bleach liquor quality, temperature
and treatment time. It is preferable to have strong bleach with short treatment
time. Care should be taken for the bleached goods so that they should be
adequately antichlor or after washed with peroxide to minimize yellowing.
Materials should be carefully stored before processing for color uniformity,
Process cycle:
Desizing
Ø Load the
garments into the washing machine (100 kg) ;
Ø Add water
(liquor ratio 1:5) and start the machine running(12-15 rpm) ;
Ø Add
amylase enzyme (1 to 3% i.e.1 to 3 kg) ;
Ø Add
detergent (1% i.e. 1kg) ;
Ø Supply
steam to raise temp.(60°C) ;
Ø Continue
the process for 20 min and then drain the liquor ;
Ø Hot wash
(at temp. of 40°C to 50°C for 5 minutes).
Bleaching
Ø Add Water
into the m/c (1:5 liquor ratio, i.e. 500 litres );
Ø Start m/c
running ( 12 to 15 rpm ) and add soda ash (Na2CO3) to liquor (2% i.e. 2kg)
Ø Add
costic soda (NaOH) to liquor (2% i.e. 2kg) ;
Ø Add
bleaching chemical (H2O2) to liquor (5ml per liter, i.e. 2.5 liters) ;
Ø Add
stabilizer to liquor (2ml per liter, i.e. 1 liter) ;
Ø Supply
steam to raise temp.(70°-800C) ;
Ø Continue
the process for 60 to 70 min. and drain the liquor ;
Ø Hot wash
(at 60°C for 5 minutes).
Neutralization
Ø Add Water
into the m/c (1:5 liquor ratio, i.e. 500 liters );
Ø Start m/c
running ( 12 to 15 rpm );
Ø Add
acetic acid ( CH3COOH ) to liquor (1 to 2 ml per liter, i.e. 500ml to 1liter);
Ø Continue
the process for 10-15 min and then drain the liquor.
Brightening treatment
Ø Add Water
into the m/c (1:5 liquor ratio, i.e. 500 litres );
Ø Add
Fluorescent Whitening agent/Fluorescent Brightening agent to liquor (% as
required );
Ø Supply
steam to raise temperature (800C);
Ø Continue
the process for 10 min and then drain the liquor.
Softening
Ø Add Water
into the m/c (1:5 liquor ratio, i.e. 500 litres );
Ø Start m/c
running ( 12 to 15 rpm );
Ø Add
softener to the liquor (0.1 to 0.5%, i.e. 100g to 500g);
Ø Supply
steam to raise the temperature (as required 400 to 600C );
Ø Continue
the process for 5 minutes and then drain the liquor and unload the garments.
Limitations of denim bleaching:
Ø Process
is difficult to control i.e. difficult to reach the same level of bleaching in
repeated runs.
Ø When
desired level bleaching reached the time span available to stop the bleaching
is very narrow. Due to harshness of chemical, it may cause damage to cellulose
resulting in severe strength losses and or breaks or pinholes at the seam,
pocket, etc.
Ø Harmful
to human health and causes corrosion to stainless steal.
Ø Required
antichlor treatment.
Ø Problem
of yellowing is very frequent due to residual chlorine.
Ø Chlorinated
organic substances occur as abundant products in bleaching and pass into the
effluent where they cause severe environmental pollution.
2. ENZYME WASH
It is environmentally
friendly wash. It involves the application of organic enzymes that eat away at
the fabric, i.e. the cellulose. When the desired color is achieved, the enzyme
can be stopped by changing the alkalinity of the bath or its temperature. Post
treatment includes final ringing and softening cycle.
The effects produced by cellulose enzyme are :—-
Ø Use of cellulose making
the seams, hems, and pockets more noticeable;
Ø Salt paper effect is color
contrast effect.
Ø Faded garment washed with
acid cellulose enzyme provides less color contrast in proportion to garment
washed neutral cellulose enzymes.
Ø
Garment load size of the m/c is 35-40 jeans per m/c and it cannot
be overloaded.
3. ACID WASH
It is done by tumbling the
garments with pumice stones presoaked in a solution of sodium hypochlorite or
potassium permanganate for localized bleaching resulting in a non uniform sharp
blue/white contrast. In this wash the color contrast of the denim fabric can be
enhanced by optical brightening. The advantage of this process is that it saves
water as addition of water is not required.It consists of soaking pumice stones
with chlorine and using their abrasive power to bleach jeans into sharp
contrasts. Also known as moon, fog, marble, ice and frosted.
Process cycle :
Desizing
Ø Load the garments into the
washing machine (100 kg) ;
Ø Add water into the
machine(1:5 liquor ratio i;e. 500 liters) ;
Ø Start machine running (12
to 15 rpm) ;
Ø Add amylase enzyme (1 to
3% i.e.1 to 3 kg) ;
Ø Add detergent
(1% i.e. 1kg) ;
Ø Supply steam to raise
temp.(60°C) ;
Ø Continue the process for
20 min and then drain the liquor ;
Ø Hot wash at temp. of 40°C
to 50°C for 5 minutes.
Bleaching
To carry out the Bleaching
process, the following two steps are to be passed over :
Step 1.
Ø Take
stone of some volume of the volume of garments ;
Ø Soak the
sfone with the following chemical solution for 2 to 3 minutes ;
Ø Water 100
litres
Ø Potassium
permanganate 1 kg
Ø Phosphoric
acid 300 ml (3ml per litres)
Ø Here the
porous of stones are dried in the open air for 60 to 90 min.
Step 2.
Ø Load the
garments treated in step # 1 and step # 2 in a dry m/c. Lot size should be 20
to 30kg.
Ø Run the
m/c for 5 to 7 minutes. Due to the rotation of m/c the socked stones will hit
the garments surfaces and the chemicals in the stone will destroy color of the
fabric. Multilayer fabric areas like collar, cuff, pocket, pocket side seam
etc. area will be brushed more than the single layer areas, therefore more
fading effect will be produced in those areas resulting new color effect in the
garments.
Ø Unload
the garments and separate the stones from the batch.
Ø In this
stage KMnO4 and H3PO4 reacts with each other and gives Oxygen which
oxidize the color. Here a byproduct MnO2 is produced which should be
neutralized.
Ø 6KMnO4 +
4H3PO4 = 2K3PO4 + Mn3(PO4)2 + 6H2O + 3MnO2 + 2O2
Ø This
MnO2 is solubilized by Sodium Metabisulfite (Na2S2O5).
Ø Na2S2O5 +
H2O = 2NaHSO3
Ø NaHSO3 +
MnO2 = MnSO4 + NaOH
Ø Load the
garments to the m/c ;
Ø Add water
into the m/c (1:5 liquor ratio, i.e. 500 litres) ;
Ø Continue
the process (12 to 15 rpm) ;
Ø Add
sodium metabisulfite (1 to 2 gpl, i.e. 500 g to 1kg) ;
Ø Continue
the process for 5 to 10 min and then drain the liquor ;
Ø Hot wash
(at 40o to 50o C for 5 minutes).
Nutralization
Ø Add Water
into the m/c (1:5 liquor ratio, i.e. 500 litres );
Ø Start m/c
running ( 12 to 15 rpm );
Ø Add
acetic acid ( CH3COOH ) to liquor (1 to 2 ml per liter, i.e. 500ml to 1liter);
Ø Continue
the process for 10-12 min and then drain the liquor.
(To be Continued in November 2013 issue)
Magazine Article :DYE CHEM PHARMA (October 2013)